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membranes for removal of carbon dioxide and water vapour from flue gas


Posting by richard pohlmann on April 17, 2008 at 16:07:10.

Hi,

I am interested in (composite) membranes for removal of water vapour and carbon dioxide from flue gases. I understood that sulfonated polyether etherketone (SPEEK) is a rather promising material for water vapour removal, but a good laminate or composite membrane that could deal with carbon dioxide gas as well, would be even more promising... Realize that the membrane material must be able to deal with the acidic mixture (carbonic acid formed by CO2 and H2O) and other flue compositions from coal fired power plants.

Do you guys have any suggestion for a long life (100.000 hours) material?

Cheers!

Richard


          follow up posts
    On 04/17/2008 composite agency posts: Dear Richard,

    Carbon dioxide gas removal from flue gas from coal plants is a rather actual subject. Here (in Holland) we have several companies who are/will be involved in Carbon dioxide capture and subsequent conveyance via pipelines and storage in natural gas / oil resevoirs to prevent global warming.

    By the way, there are technical specialists who claim that carbon dioxide is not causing global warming, but water vapour. In modern society, the exhaust of water is several magnitudes larger than carbon dioxide...

    However, we are not specialists in global warming, so back to your issue. Taking the above into account it is a good idea to capture water as well as carbon dioxide from flue gas in one step (for several reasons).

    We have some experience with sulfonated polyether etherketone (s - peek). Very probably there are more effective materials available for water removal (however the processing conditions are not clear in this tage). If you want to remove carbon dioxide, you should use at - low water humidities - a laminate solution based on a water selective membrane and a carbon dioxide gas selective membrane like poly dimethylene siloxane (pdms).

    Hope this helps ;-)

    Best Regards,
    [responses: 2]

      On 04/17/2008 bernard posts: I am looking to the same issue, but from another direction. I am interested in possible relining/coating materials for existing steel (stainless & high strength) pipeline in case of carbon dioxide transport. We als have to assume that water is present. The pressure conditions are approx. 100 bar and the temperature is ambient. What sort of coating / lining do you suggest for CO2 storage?

      Danke,

      Bernard
      [responses: 1]

        On 05/05/2008 johny mechanical posts: Why do you need a special CO2 barrier coating? To prevent CO2 diffusion through the welds / joints? If diffusion is not an issue in case of methane and natural gas transport, why bother in case of carbon dioxide conveyance?

        Johny
        [responses: 0]



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