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The primary economic barrier preventing the use of fibre and particles reinforced plastic materials is often their high initial cost, whereas the primary technical hurdle remains the relative uncertainty about the long-term performance of composite structures in their service environment. This is a pity, while polymer based composite materials are often attractive materials from the viewpoint of weight, mechanical strength and maintenance costs.
The uncertainty with regard to service life predictions is often caused by lack of an integrated engineering approach. This approach is of major importance since composite material characteristics are rather complex when compared to other, for example cast metal materials. An integrated assessment of the material takes the development of mechanical, corrosion and permeation properties into account, simultaneously. Modern computer simulations based on mathematical methods, like the infinite difference method, and key figures based on laboratory experiments on polymer and composite samples, enable us to carry out these integral assessments.
Below you will find two real life based case studies that give an impression of our integrated approach. In case study II, the diffusion of water is connected with an internal corrosion mechanism, which subsequently influences the mechanical properties of the polymer composite material. In case study I, blister and bulge formation on composite materials is described. Blister formation on gelcoats, field joints, aluminium coatings, and so on, can be described in a similar manner.
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| case study II: service life of glass fibre reinforced polyphenylene sulfide |
[Summary] This paper discusses the mechanical ageing or fatigue of carbon, glass fibre, aramid and particle filled thermosets (epoxy, vinyl ester, polyester, polyurethane resins) and thermoplastic (polyether etherketone, polyphenylene sulfide, liquid crystal polymers) when the material is exposed to water and aqueous solutions (acidic, alkaline). Water and related molecules, are small, hence they diffuse relatively fast, and have an intrinsic hydrolysis reaction capability. This behaviour alters the conditions of the interface between matrix and reinforcement (interlaminar shear strength, ills) and subsequently decreases the tension and compression properties of the material. Click here to read the study.
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| case study I: service life of glass fibre reinforced polyphenylene sulfide |
[Summary] In part I, the parameters relevant for blister, bulge and griffith crack formation on top of - or inside - reinforced material are discussed thoroughly. The methodology is based on uptake experiments, raman spectroscopy and pressure blister measurements. In this study it appears that blister formation initiated by a nucleus on top of fibres is a thermodynamically unfavoured situation. The elastic energy release generated by blister growth is much too small to overcome the interfacial surface energy or interlaminar shear strength. So absorption of water in the composites material, driven by osmotic pressure, is highly uncertain. However hydrolysis reactions take place at the interface, and this conversion of water into for example an acid and alcohol, influences the water absorption of a reinforced thermoset or thermoplastic material. In part II, this absorption with simultaneous chemical reaction will be quantified and related to decrease in mechanical characteristics of the composite. Click here to read the case. |
| Actual and interesting forum threads: |
| - ageing pipeline field joint coating made form polyurethane |
| - behaviour of interface of polypropylene-aluminum-polypropylene multilayer pipeline |
| - advanced computer programmes for life time predictions of plastic matrix composites |
| - adhesion of metal on epoxy resin |
| - ageing of fibre reinforced epoxy lining, applied for repair of a corroded steel pipeline for oil |
| - lifetime prediction of aluminum epoxy composite |
| - composite materials for civil infrastructure such as bridge joints and bridge decks |
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