case stories
1: service life behaviour of thin film flexible solar cells
In this case study the lifetime of a thin film flexible solar cell is assessed.
The multilayer solar cell will be applied in curved body parts for vehicles.
The long term mechanical and corrosion resistant properties are focus of the study.

For sake of corrosion prevention of the subsequent functional layers, on one hand
crystallinity and thickness of the transparent surface polymer must be as high
as possible. As such, the permeation rate of Oxygen and Water through the surface
layer is kept low. On the other hand, adhesion of the polymer to the substrate
decreases as function of thickness. The robustness of the interface is of
major importance in restraining the mass solubility and temperature driven
expansion stresses and mechanical stresses at the surface. To complicate things
even more, the impact resistance / fracture toughness of the surface polymer
decreases as function of the degree of crystallinity.

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2: (hygrothermal) ageing and fatigue of composite rotor blades
Proper mechanical and corrosion resistance properties of polymer based materials is
of major importance in many applications. Traditional chemical resistance guides can
provide valuable information with this regard.

However, analysis becomes more complex if the polymer is reinforced with filler
material and is sequenced in a composite laminate. Because of the discontinuous
nature of diffusion rate, solubilities and restraints in the different layers, corrosion
prediction and forthcoming mechanical retention of the composite is still a concern
for long term rotor blade operation.

Here, we demonstrate an integrated diffusion-chemical-mechanical approach for
composite service life prediction of a composite rotor blade, going beyond the
standard lifetime of 20 years. We use CheFEM software for chemical driven
degradation (salt water, bird droppings, UV light) in combination with existing FEA
multiphysics tools for rigorous stress / strain modelling.

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3: using epoxy coating for pipeline retrofitting
In the near future, natural gas pipelines (type X-52, X-60, X-65 and X-70) may also
be used for transport of Hydrogen or even Carbon Dioxide. In case of Hydrogen
conveyance, Hydrogen might be mixed with Natural Gas (parallel gas transport,
using a membrane to seperate the gases at the outlet) or transported solely.
Discarded natural gas pipelines may also be completely retrofitted for Hydrogen or
Carbon Dioxide transport. With regard to Hydrogen, a service life concern could be
HISC (Hydrogen Initiated Stress Cracking) of steel. Hydrogen embrittlement or HISC
results from combining of diffusing Hydrogen atoms into molecular Hydrogen - or
the formation of molecular Methane - in internal metal voids of nanoscopic size.
The generated pressure - in combination with intrinsic circumferential stress in the
material - can exceed the restrain pressure of steel, especially near the loading
surface. Whether HISC is an issue is largely dependent on the sort of steel,
internal pressure and temperature. (continued on next page)

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4: carbon dioxide diffusion loss from PET bottle
An interesting case is the diffusion of CO2 (carbon dioxide) through the wall of a
PET (Polyethylene Terephthalate) bottle that contains soft or alcoholic drinks. You
can think of cola or beer. Reason for putting gaseous CO2 in drinks is taste.
The gas gives a sparkling feeling and a reduction in tasted sweetness.

One can imagine that diffusion of CO2 through the wall is a problem because of loss
of these features in time; in other words, a loss of quality in time. In this case story,
the CO2 diffusion from a bottle as a function of time is demonstrated in real-life
circumstances.Carbon Dioxide Diffusion from PET

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5: composite water permeation and chemical resistance
In new composite equipment, such as in windmill turbines, aerospace parts, body
parts for car and trains, electronic packages, medical packaging, membranes for
simultaneous carbon dioxide / water vapour removal and other membrane
applications, the mechanical retention if the composite is exposed to hygrothermal
conditions is one of the main interests.

The fact that water diffuses with a considerable rate in polymers, in combination with
the anomalous diffusion and uptake behaviour, have lead to a variety of different
theories with regard to water behaviour in composites. In this preliminary paper we
present our view on water diffusion and mechanical retention in an unreinforced and
glass fibre reinforced Derakane 411 Epoxy Vinyl Ester Resin.

We have used CheFEM to interpret gravimetric data using two main concepts:
[1] localized water adsorption theory, [2] multilayer diffusion simulation.
The composite configuration that we tested did not show chemical degradation, but
swells to a small extent under the continuous load of water. composite chemical resistance in hygrothermal conditions

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6: polyimide for flexible thin film solar cells
One of the candidate substrate materials for polymer based solar cells and Organic
Light Emitting Diodes (OLED's) are transparant polyimides. Because of their
combination of mechanical, moisture barrier and corrosion resistance (among which
are UV light and extreme high Oxidation resistance) properties - even at high
temperatures - they might be suitable.

In this case study the water absorption characteristics of a new polyimide in real life
circumstances is evaluated. By means of gravimetric, free volume and electrical
impedance (EIS) data, it is found that water absorption in this specific polyimide can
be rigorously modelled using the dual mode sorption model. According to this
model, a part of the water molecules is adsorbed on hydrophilic sites in the polymer
with a Langmuir isotherm. This part is immobile. Another part dissolves in the
polymer and can move by normal (Fickian) diffusion. The implications of this
significant anomaly on water breakthrough times, on water mass flux into the
device, on accelerated weathering tests and on dimensional change are explained
thoroughly. water diffusion polyimide based solar cells

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7: lifetime prediction of thermoplastic joint for bridge decks
Thermoplastics joints have been developed to solve the corrosion problem of
bridges, sluices, dams and other structures. The different steel reinforements are to
a greater or lesser extent susceptible to corrosion in the highly alkaline environment
of concrete. As a consequence, the thermoplastic joint could provide some basic
protection for the less durable materials solutions against diffusion and
deterioration. In this paper, the combined aqueous immersion and sustained stress
on the service life of a plastic joint is chararacterized. This is done by mechanical
testing and simultaneous chemicals exposure.osmosis in composite materials

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8: 100% nitrogen in car/motor cycle tyres
Usually we fill our tyres with Air. Nowadays there are several discussions in
magazines and internet on whether it would be better to fill tyres with 100%
Nitrogen or Carbon Dioxide instead of Air. The diffusion resistance layer of tyres are
made from a polymer rubber called Polyisobutylene, and a few percent of Isoprene.
In this case history it is shown that this polymer has a better diffusion resistance
against Nitrogen than Oxygen. Moreover the practical implications of this difference
are described.Pure nitrogen in tyres

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9: methanol diffusion in GFRP
Here we demonstrate how mass transfer of liquids and saturated vapours is applied
in an industrial application. We were commissioned to assess whether it is possible
to use a GFRP (Unsaturated Polyester Glass Fibre Reinforced Plastic) pipeline for the
transport of methanol. Apart from past effects of alkaline water transport on
sustainability of this pipeline, it is shown how the methanol flux changes in the time
period evaluated. In this example the counter diffusion of polluting chemicals in
ground water was not taken into account.Methanol Diffusion GFRP

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10: polyethylene liner on tank for gasoline
In a wide range of industries, various composite and lining systems are used with
the objective to combine good mechanical and chemical resistance properties. Key to
a sustainable and - sometimes even - a multi-purpose service life, is chemical
resistance and diffusion analysis in an early development stage. The case of gasoline
in a HDPE lined / coated Epoxy tank gives a clear insight in our approach. We have
more information available on similar configurations, like hoses, tubes, adhesives,
rubbers and elastomers for gasoline based on PA, PVDF, PPS including different
kinds and degrees of reinforcements.Gasoline Diffusion HDPE Epoxy

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11: using Hildebrand solubility parameters for material selection
We want to assess what sort of thermoplastic polymer we can use for containment
of toluene at ambient conditions. A special design requirement is prevention of
plasticizing of the material by toluene. This requirement is related to diffusion
resistance: in many instances plasticizing causes the initial diffusion rate to increase
several orders of magnitudes. This can be noticed from the figures in the table for
liquid diffusion on the website. If a chemical has a high solubility in the polymer, then
the weighted average diffusion rate (D|) becomes much larger than the initial rate
(D0).solubility parameters for polymer material decision

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12: hygrothermal resistance of epoxy - polyester composites
In glass fibre reinforced plastics (GFRP) or glass fibre metal laminates (FML's) the
combination of the different components do substantially increase the mechanical
properties of the material, think for example of high toughness, very long critical
crack lengths, etc. At the same time the behaviour of these materials when exposed
to chemicals, high pressure and high temperature is becoming more and more
complex.

For fully integrated chemical-physical service life time predictions, the situation at the
interface should often be the focal point of analysis and simulation. Here, possible
voids do appears, temperature or swelling stress beyond the interfacial strength
may come into play, cohesive strength, adhesive work, interlaminar shear strength
values, pull and peel tests, etc. The attached paper is one of our first works on this
subject and was published in the framework of ESAT 2006.materials

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