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diffusion of ethanol/propellant through EPDMPosting by russell walker on May 06, 2008 at 17:54:54.
Hi, I have an aerosol application where EPDM (Ethylene Propylene Diene Monomer) is being used as a seal. The contents consist of a propellant (HFA-227) and Ethanol. We have conducted some experiments and the container appears to be losing ethanol at a much faster rate than the propellant. Elevated temperature accelerates the loss. The two contents are not coming out at proportional rates. The ethanol is coming out at ~10x rate. The molecular weight of Ethanol is smaller than the propellant (46 vs. 170) but its boiling point is higher and its partial pressure and concentration (almost 100x more propellant) in the container are lower. Does this sound like Ethanol is diffusing through the EPDM or does another mechanism explain what I am seeing? Thank you,
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